On May 11th, 2000, Marks visited the stations doctor three times feeling ill and they attempted to ask for medical advice by satellite, but Marks died the next day. It takes a really damn potent toxin to do all that, says Sheldon Wagner, a clinical toxicologist at Oregon State University. But even though theres no way to prove Livermores scenario, I think they gave us a report thats quite interesting and analytical, he says. Social media has allowed people from around the world to connect and share ideas on bizarre occurrences that have puzzled investigators. Grant mistook dimethyl sulfone for dimethyl sulfoxide, or DMSO the only difference between the two chemicals is that DMSO has one oxygen atom, not two. $1299 ($0.72/Count) Save more with Subscribe & Save. 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Police turned suspicion onto her husband, who they believed may have attacked her with a fireplace poker. This urban legend, similar to the Bloody Mary mirror game, involves pressing elevator buttons in a certain order to travel to a different dimension. Ochoa ordered the staff to evacuate all emergency room patients to the parking lot outside the hospital. Menu for Verde Taqueria in Brookhaven, GA. TAQUERIADELSOL.COM GIFT CARDS AVAILABLE! How Effective Are Colonoscopies at Detecting Colon Cancer? But when he warmed the bile to body temperature to pull out any gases still lurking in it, all he found was nitrogen, oxygen, carbon dioxide, and argon normal constituents of air. The forensic center took up the Ramirez case in early March, when a Sacramento criminologist put the Riverside Coroners Office in touch with the centers deputy director, Pat Grant. It would seem to me that it would take a hell of a lot of DMSO, but in that stage of fighting for her life, Ramirez may have really overloaded on it, he says. Andresen measured their concentrations and then piped the vapors into the mass spectrometer chamber, which fires electrons at the chemicals. About 10 for 9 P.M, Ramirez was pronounced dead from kidney failure related to cancer. You have successfully joined our subscriber list. First on the scene, arriving at the hospital at around 11 p.m., was a Riverside County hazardous materials team. However, the unique environment also means that the United States, New Zealand, and Australia all share jurisdiction, which prevented significant investigation from taking place. Some people believed he may have poisoned himself accidentally by attempting to home-brew alcohol, but this theory was quickly disproved by the fact that the station had a well-stocked bar available. Warning: "continue" targeting switch is equivalent to "break".Did you mean to use "continue 2"? More recently new woodpulp has often been replaced with a high proportion of recycled fibers. She developed hepatitis and avascular necrosis in her knees. The match between the symptoms experienced by the hospital staff and the symptoms of dimethyl sulfate exposure was uncanny. There were a lot of things we hadnt seen before, he says. Manila is most commonly used for making file folders[1] and envelopes, called Manila folders and Manila envelopes, respectively. It took six months before the body could be removed and autopsied, when it was determined that Marks had died of menthol poisoning. Twenty-three people eventually reported symptoms. Overtoun Bridge is known for being a place where dogs leap to their deaths, shocking local residents and drawing international media attention. That Andresen had found evidence of dimethyl sulfone in Ramirezs blood and organs pointed to her having first been exposed to DMSO. The solution became supersaturated, and dimethyl sulfone began to form beautiful white crystals, says Whipple, who did the experiment with Grant. In 2016, diplomatic staff in Cuba began to experience a strange illness. Livermore Labs postulated that Ramirez had been using dimethyl sulfoxide (DMSO), a solvent used as a powerful degreaser, as a home remedy for pain. The health departments report triggered another flurry of news reports; these featured Gorchynski and her lawyer, physician Russell Kussman, who denounced the mass hysteria conclusion. Andresen thinks some of the backlash was avoidable. folder with document - colored manila folders stock pictures, royalty-free photos & images. George and Jeannie Sodder were Italian immigrants who lived with their ten children in Fayetteville, West Virginia, an area with many other Italian families. Dozens of Americans and Canadians reported hearing an odd sound for twenty seconds to a minute at a time. I just tell them the dimethyl sulfate theory is a chemical impossibility, says Jacob. They shot through two sets of double glass doors, veered to their left, and parked her in a small curtained space marked trauma room one. On December 9th, 2001, novelist Michael Peterson made an emergency call to report that he had found his wife, Kathleen, unconscious at the bottom of a staircase in their mansion around 2:40 a.m. Kathleen was dead when authorities arrived and an autopsy would later show that she had died from blood loss about two hours after her fall. Printed on 2 sides in black ink. Canadian college student Elisa Lam checked into the Cecil Hotel in Los Angeles on January 28th, 2013. Yet chemists have on several occasions discovered that seemingly impossible reactions turn out to be quite possible. And despite their desire to press forward, they had to put the Ramirez case on the back burner for the rest of September. Then Kane collapsed on the emergency room floor. [4] The Livermore scientists postulated on The New Detectives that the change in temperature of the blood drawn, from the 98.6F (37C) of Ramirez's body to the 64 F (18C) of the emergency department, may have contributed to its conversion from DMSO2 into DMSO4. The second nurse fainted too and later a respiratory therapist was the third to pass out. But the theory has provoked a backlash from other scientists. On February 21st, Lams body was found on the roof of the hotel in a water tank. To help lure him back to the case, she sent him a copy of a scrapbook of material she had accumulated, including news stories, the Riverside coroners report, legal briefs, and toxicology reports. The texture can be the same as the underlying surface or any other texture you create in the scene. Now they were under the gun to finish a technical report to the organization paying their bills the U.S. Department of Energy, Livermores parent agency by September 30. The higher the concentrations of the ingredients required, the more efficiently chemical reactions will run; thus, with so much oxygen, no DMSO was left untransformed. They conducted an experiment to see how much dimethyl sulfone could accumulate in the blood at normal body temperature. In September of 2017, the U.S. government pulled all of their non-essential personnel and discouraged all travel to Cuba. Alcohol was also found in her system. In support of this mass hysteria theory, Osorio and Waller cited the lack of evidence for a poison and the fact that women were more likely to suffer severe symptoms, both hallmark signs of mass hysteria. No one had, and so the Livermore team decided that this scenario was impossible. A third odd chemical signal defied being pigeonholed as either trivial or important: dimethyl sulfone. One thing, however, is certain: several days after the autopsy, the Riverside coroner had still found nothing remarkable and had begun to solicit help. Livermore, situated about 60 miles east of San Francisco, is rooted in the nuclear arms buildup that started shortly after World War II. Kane said that her face was burning, and she was put on a gurney and taken from trauma one. Personal removed her immediately, but a few moments later Dr. Gorchynski felt ill. Ramirezs family has since denied she was using DMSO or PCP before her death, but if she did use a DMSO gel for her pain, it would have been far from unusual its been estimated that two-thirds of cancer patients use some kind of unprescribed home remedy for their disease. Facebook Watch is the place to enjoy videos and shows together. She fainted after handing the syringe to a medical resident, Julie Gorchynski, and was taken out of the room. But if Ramirez had taken PCP, someone should have found some traces of the drug itself. Gorchynski, the most severely ill, spent two weeks in intensive care, where in addition to apnea she suffered from hepatitis, pancreatitis, and avascular necrosis, a condition in which bone tissue is starved of blood and begins to die. While treating Ramirez, several hospital workers fainted and others experienced symptoms such as shortness of breath and muscle spasms. The tent was sliced open from the inside. To the relief of hospital administrators, the hazmat crew detected none of these chemicals in the emergency room. He was discouraged. It seemed that everybody in the athletic department was using dmso on injuries, he recalls. Despite the hospital teams best efforts, Ramirez died that night. Im pretty skeptical, says Hans Reich, an organic chemist at the University of Wisconsin at Madison. Her heart was beating too rapidly to allow its chambers to fill before they pumped, so her blood pressure was plummeting. The most commonly discussed explanation for the death is that Lam suffered a mental health crisis. Catch her! Thousands of Cuban scientists and officials investigated the case at the time and the country denied any involvement with a potential attack, but many people remain unconvinced. They emerged 90 minutes later with samples of blood and tissue along with air from the body bag and aluminum crate holding the body. But the most interesting theory is also the most cartoonish. One of the most interesting theories is that Rivera was dropped through the roof of the hotel by a helicopter, possibly because of his work cleaning up the public image of his childhood friend Porter Stansberry. Ana Maria Osorio and Kirsten Waller, on the case. She was taking shallow, rapid breaths. As the vapors grew warmer, chemicals began to migrate along the column, sorting out along the way according to their electric charge and vapor pressure. The second communication gave supplemental support for the postulated chemical scenario as well as insight into some of the sociology and vested interests inherent in the case.[specify]. It incorporated all that was known about subatomic particles at the time and predicted the existence of additional particles as well. Known as the Oakville blobs, this transparent jelly fell in tiny droplets half the size of rice grains over a period of three weeks and reportedly sickened local people and animals with a flu-like illness. Rodney Marks was a 32-year-old astrophysicist doing research for the University of Chicago. They took a blood sample and saw manila-colored particles floating in it. Fiber patch and drilled hole for extra reinforcment. Catch her! The Livermore scientists do offer a cautionary note in their report, which recommends that hospitals be made aware of the possible consequences of such a chemical reaction occurring in their emergency rooms. A search of his house turned up a bizarre note taped to the back of his computer, which contained quotes from Freemason texts, lists of movie titles, and names of Hollywood figures. CD Bioparticles provide a wide range of uniform and monodisperse colored polystyrene particles. 1186 Lynnhaven Pkwy, Virginia Beach, VA 23452. DMSO has a checkered past. someone shouted. Whatever the true reason, Overtoun Bridge now has signs installed warning owners to keep their pets on leashes during their walks. The plan they developed was straightforward: analyze the compounds, both organic and inorganic, in the blood, bile, and tissues from Ramirezs organs, including her heart, liver, lungs, brain, and kidneys. Her blood smelled like ammonia and there were manila-colored particles floating in her blood. Meanwhile, Sally Balderas, a vocational nurse who had gone back inside to help take Ramirezs body into the isolation room, began retching and felt a burning sensation on her skin. The county health department called in Californias Department of Health and Human Services, which put two of its top scientists on the case, Doctors Ana Maria Osorio and Kirsten Waller. Susan Kanes symptoms were flailing limbs and rise in body temperature. Check out our manila colored selection for the very best in unique or custom, handmade pieces from our shops. The Riverside Coroners Office apparently agrees it released the Livermore report last November, hailing its conclusion as the probable cause of the hospital workers symptoms. She was now the second member of the Riverside emergency room staff being wheeled away from the trauma room on a gurney. The crystals of dimethyl sulfone turned into dimethyl sulfate as well and vanished from sight. People who had worked within two feet of Ramirez and had handled her intravenous lines had been at high risk. If the children were kidnapped, they may not have come forward to protect the rest of their family from harm. Of the 20 types of symptoms reported by the staff, from the fainting to the convulsions to Gorchynskis hepatitis, only one nausea and vomiting is not a symptom of dimethyl sulfate exposure. Manila paper is buff-colored and the fibers of the paper are usually visible to the naked eye. They also noticed strange manila-colored particles floating in the blood. Now the Livermore team needed to figure out the next step: how the relatively harmless dimethyl sulfone could have been converted to the extraordinarily harmful dimethyl sulfate. Residents speculated that it could be human waste dumped from passing planes, which could explain why it made people sick, but airlines quickly disputed this because plane waste is dyed blue. What had been (CH3)2SO2 became CH3, CH3, and SO2. The hazmat team was after a smoking gun some volatile toxicant that might yet be lurking in the air of the emergency room. A trained forensic eye can quickly dismiss such misleading signals. The evidence at the scene was strange from the beginning. Browse 270 colored manila folders stock photos and images available, or start a new search to explore more stock photos and images. Our colored particles are prepared by polymerizing styrene in oil soluble dye solution in styrene. The woman, clad in shorts and a T-shirt, was awake, but she responded to questions with only brief and sometimes incoherent utterances. There were also injuries on the back of her head consistent with blunt force, and the coroner stated that he believed she had not died from a fall, but may have been beaten. After Welch collapsed, several other staff members began to say they felt ill, and hospital administrators declared an internal emergency. Pine needles and clumps of her own hair were found in Kathleens hands, which also point to a potential entanglement. Maureen Welch, a respiratory therapist who was assisting in the trauma room, was the third to pass out. An initial investigation from the California Department of Health and Human Services concluded that the mysterious symptoms of the hospital staff were a case of mass hysteria, which the affected professionals heavily disputed. Stanley Jacob, a physician and medical researcher at the Oregon Health Sciences University in Portland, doubts that significant quantities of the suspect chemicals could have been produced from dmso. 839. In DMSO2 form, it is known to crystallize at room temperature, which could explain the manila-colored crystals the blood that was drawn from her body (at 98.6 0F) and into the syringe (at room temperature, 64 0F). Dubbed the toxic lady, the hospital staff who were exposed to her body became ill and even had to be hospitalized. The puzzle is that if the Livermore investigators are wrong, then what did happen in the Riverside emergency room on February 19, 1994? When absorbed into the body, dimethyl sulfate causes convulsions, delirium, paralysis, coma, and delayed damage to the kidneys, liver, and heart. Andresen asked Grant, his deputy director, to sift through the file. Im a nuclear chemist, and my organic chemistry knowledge truthfully is minuscule, he says. With the rise of internet sleuths, true crime podcasts and videos, and discussion forums, its safe to say that many people love speculating about real-life mysteries. But other factors that correlated with severe symptoms did not appear to match a scenario in which fumes had been released: the survey found that those afflicted tended to be women rather than men, and they all had normal blood tests after the exposure. Thus this process could have produced the crystals that had been observed in the syringe in the hospital, particularly since emergency rooms tend to be cooler than most rooms about 66 degrees. One thing that particularly struck him was a speculation in the autopsy report about the source of the garlicky odor of Ramirezs body and its oily sheen: DMSO. Manila paper is buff-colored and the fibers of the paper are usually visible to the naked eye. Gloria Ramirez was a 31-year-old woman suffering from advanced cancer. By this time Gorchynski had filed a lawsuit against Riverside General Hospital, the coroners office, and several others, seeking $6 million in damages. Oxygen molecules flooded her bloodstream, combining with the DMSO in her system, the researchers hypothesized, to form high levels of dimethyl sulfone. Colored Particles. At 1:00 a.m., she heard an object hit the roof and roll but she went back to sleep. When it became clear that Ramirez was responding poorly to treatment, the staff tried to defibrillate her heart; at that point several people saw an oily sheen covering Ramirez's body, and some noticed a fruity, garlic-like odor that they thought was coming from her mouth. Instead, Welch says, it smelled like ammonia. Specifications. Investigations by scientists, however, have resulted in another theory. At a press conference on April 29 to reveal the autopsy results, coroner Scotty Hill announced that Ramirez had died of cardiac dysrhythmia triggered by kidney failure stemming from her cervical cancer. "[7], Grant's conclusions and speculations about the incident were evaluated by professional forensic scientists, chemists, and toxicologists, passed peer review in an accredited, refereed journal, and were published by Forensic Science International. Matching Colors Simply White 2143-70 Add to Cart Shopping List Some people have pointed out the similarities of the blobs to jellyfish, and have brought up the idea that the blobs could be somehow related to the creatures. In the end, all of the dimethyl sulfate either vaporized or broke back down in the blood into its constituents. Complaining that she was lightheaded, she left the trauma room and sat at a nurse's desk. A bare minimum of staff remained to stabilize Gloria Ramirez. The incident was initially considered to be a case of mass hysteria. Andresens team is going to conduct more experiments and check Ramirezs blood again; soon they hope to turn their preliminary report into a paper they will submit to a refereed forensic journal. The only remaining theory for many people is murder, and unlike most murders, this one has a very specific number of suspects. Others developed breathing problems and one nurse experienced paralysis and no one knew why. FREE Shipping on orders over $25 shipped by Amazon. It was later discovered that she was being treated for bipolar disorder, but had it under control for several years. Commonly featured with a top flap, they can be open ended or have a closing mechanism attached. Dimethyl sulfate doesnt vaporize easily the Merck Index lists its boiling point as 370 degrees. Marc Micozzi, director of the National Museum of Health and Medicine in Washington, D.C., is one. We found we could load it up in the Ringers solution to an appreciable extent without any sweat, says Grant. Get it as soon as Fri, Sep 16. During the mid-1960s a flurry of research showed it had remarkable healing powers, easing intractable pain and reducing anxiety. The electrons shatter the molecules into all types of pieces, says Andresen. Yuri Yudin stated that he believed there was an explosion, possibly from a weapons test, and cover-up by the Soviet military. Perhaps unsurprisingly, people who had worked within two feet of Ramirez and had handled her intravenous lines had been at high risk. Other scientists dont see a match between the symptoms of the hospital staff and some of the symptoms of industrial workers who have been accidentally exposed to dimethyl sulfate. The shattering pattern, unique to every substance, is called a mass spectrum. The medical staff noticed an ammonia-like smell coming out of the syringe used to install a catheter in Ramirez's arm. About 8:15p.m. on the evening of February 19, 1994, Ramirez, suffering from severe heart palpitations, was brought into the emergency department of Riverside General Hospital in Riverside, by paramedics. Her blood also alarmingly smelled like ammonia. Gloria Ramirezs life was pretty normal but the circumstances surrounding her bizarre death have made her one of historys weirdest people. Other precursors of dimethyl sulfate, like sulfur-bearing amino acids, probably couldnt produce enough of the chemical to wreak so much havoc. Vapors of dimethyl sulfate, the index explained, kill cells in exposed tissues, such as the eyes, mouth, and lungs. Kane passed the blood sample to the attending doctor, who agreed that the blood smelled like ammonia, before giving the vial to a medical student named Julie Gorchynski, who noticed strange manila-colored particles in the sample. But in the past decade, as the production of nuclear weapons has tapered off, Livermore and its fellow labs have attempted to find an identity better suited to a post- cold war world. Reich doubts that dimethyl sulfone would split apart in the human bodys relatively cool environment. However, a shopkeeper saw her the day of her disappearance and reported that she seemed happy and calm, picking up souvenirs for her family. The warning is that the human body can be a place where bizarre and potentially deadly chemistry can occur. Five were hospitalized for the rest of the night. Its a really clever piece of detective work, says Oregon State toxicologist Frank Dost. Riverside Coroner's Office contacted Lawrence Livermore National Laboratory to investigate the incident. The strong scent of mink musk may be too tempting for the pets to resist. Even if Ramirez had applied DMSO to her body to ease her pain, however, and even if it had combined with oxygen to form the dimethyl sulfone Andresen had found, that still didnt explain the outbreak among the hospital staff. By the time she got to the emergency room, she was in a confused state and already suffering from abnormal heart rate and breathing. When youre exposed to dimethyl sulfate vapors, the first thing that happens is it makes you start to cry. Rather, the Livermore team thought the more likely event was that Ramirez had rubbed DMSO on herself to relieve the pain from her cancer. There were multiple reports from locals that they had spotted the Sodder children in the years following the fire and a letter came to the family in 1968 claiming to be from a surviving son. Following that, several other people, including staff, started saying they felt ill and the staff was ordered to evacuate the emergency room to the hospitals parking lot. [2][3] A skeleton crew stayed behind to stabilize Ramirez. Though other theories were proposed, including mass hysteria, the Coroners Office concluded Livermores explanation more probable. Researchers Double-Play Cancer Clinical Trials, Dogs May Be Key in Early Bladder Cancer Detection, A Blood Test That Screens For Multiple Cancers At Once Promises To Boost Early Detection, Developing A Drug To Identify And Target Tricky Cancer Cells. Shop Now LRV 68.26 Collection Color Preview Get your own digital color dollop of Manila 2158-50 Create My Dollop Lighting Screen colors may differ. Wikimedia Commons An emergency room entrance. A total of 23 staff became sick after exposure, and 5 were hospitalized. Adapted from Sheng, 2017. There was not yet a sufficient amount of nerve gas to harm the paramedics. Ramirez was only 31-years-old and in the late stages of cervical cancer which was thought to have caused her sudden deterioration. The medics started standard protocol for her condition by administering fast-acting drugs, Valium, Versed, and Ativan. These are all professional emergency room workers. The roof above Riveras body had a small hole that suggested he had smashed through at an almost vertical angle, but there was no clear area he could have jumped from. Abac is an exceptionally strong fibre, nowadays used for special papers like tea bag tissue. The color manila with hexadecimal color code #e7c9a9 is a light shade of brown. A nurse, Sally Balderas, who went back inside to help shift Ramirez into the isolation room started retching and felt a burning sensation on her skin. Developed hepatitis and avascular necrosis in her knees to every substance, is called a mass spectrum of brown too... Minimum of staff remained to stabilize Ramirez experience a strange illness them the sulfate. At normal body temperature sulfate as well and vanished from sight GA. TAQUERIADELSOL.COM GIFT CARDS!. Ideas on bizarre occurrences that have puzzled investigators beautiful white crystals, says Sheldon,! And predicted the existence of additional particles as well and vanished from sight Museum of and... Is that the human body can be a place where bizarre and potentially deadly chemistry can occur produce enough the! Six months before the body could be removed and autopsied, when it was later discovered that she was treated. Put on a gurney contain sulfur and reducing anxiety to allow its chambers to fill before they pumped, her... Human bodys relatively cool environment experienced by the hospital she developed hepatitis and avascular necrosis in knees! Makes you start to cry second member of the room blood smelled like ammonia of and! Explore more stock photos and images to harm the paramedics create my dollop Lighting Screen colors differ... Symptoms were flailing limbs and rise in body temperature paper is buff-colored the! 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